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Reaction of nickel and zinc triflates with the tridentate leucoverdazyl 1-isopropyl-3,5-di (2′-pyridyl)-6-oxo-2H-tetrazine (dipyvdH) and triethylamine resulted in the neutral coordination compounds M(dipyvd)₂(M = Ni,Zn). In acetonitrile, both compounds undergo two one electron oxidation processes, Zn (dipyvd)₂ at −0.28 V and −0.12 V and Ni(dipyvd)₂ at −0.32 V and −0.15 V vs ferrocene/ferricenium. Oxidations are ligand based resulting in an intermediate mixed valence species and a cationic bis(verdazyl) compound respectively. Oxidation of the ligand changes a localized, antiaromatic, non-planar 8π electron anion to a planar, delocalized 7π electron radical. The change in ligand structure results in an increase in the octahedral ligand field splitting from 10,500 cm^–1to ∼13,000 cm^–1, suggesting an increase in the pi acceptor character of the ligand. In the mixed valence species, spectroscopic data suggests minimal interaction between ligands mediated by the metal center; i.e., these are class I-II systems in the Robin-Day classification. 

Liveness Detection (LivDet)-Face is an international competition series open to academia and industry. The competition’s objective is to assess and report state-of-the-art in liveness / Presentation Attack Detection (PAD) for face recognition. Impersonation and presentation of false samples to the sensors can be classified as presentation attacks and the ability for the sensors to detect such attempts is known as PAD. LivDet-Face 2021 * will be the first edition of the face liveness competition. This competition serves as an important benchmark in face presentation attack detection, offering (a) an independent assessment of the current state of the art in face PAD, and (b) a common evaluation protocol, availability of Presentation Attack Instruments (PAI) and live face image dataset through the Biometric Evaluation and Testing (BEAT) platform. The competition can be easily followed by researchers after it is closed, in a platform in which participants can compare their solutions against the LivDet-Face winners.